Wood ash has the properties to be an effective liming material, and research is needed to compare its effectiveness relative to agricultural lime on acidic agricultural soils. Wood ash at a calcium carbonate rate of 6.72 t ha -1 was compared with an equivalent rate of agricultural lime on a clay loam soil with an initial pH of 4.9. Replicated plots were managed under a barley ( Hordeum vulgare L.)-canola ( Brassica rapa L.)-pea ( Pisum sativum L.) rotation for 4 yr (2002-2005). Soil pH increased in the order of: wood ash=lime > control (without lime or wood ash). Available soil P increased in the order of: wood ash > lime ? control. The effect of wood ash and lime application on pH and available P was greatest in the 0- to 5-cm depth, less but still significant in the 5- to 10-cm depth, and not significant below 10 cm. The effect on soil aggregation was: wood ash > lime > control. Averaged over 4 yr, application of wood ash increased grain yields of barley, canola, and pea by 49, 59, and 55%, respectively, compared to a corresponding increase of 38, 31, and 49% by agricultural lime. The increase in crop yield with wood ash compared with lime is attributed partly to increased P availability in wood ash-amended plots. It is concluded that wood ash applied at rates equivalent to agricultural lime improved some soil chemical and physical properties and increased crop production relative to agricultural lime.
