The low natural fertility of Oxisols in the Cerrado region makes some crops in this region very dependent on high rates of synthetic N-fertilizers, which are of growing environmental concern as a major source of N2O emissions in agriculture. In a field experiment, we quantified direct N2O emissions and NH3 volatilization (a source of indirect N2O emissions) from surface-applied N fertilizer on a no-till maize (Zea mays L.) crop in Cerrado biome. We used four fertilizers at the rate of 120kgNha-1 as topdress-N (V4-V6 growth stage), which were regular urea, urea+zeolite, calcium nitrate and ammonium sulfate, and a non-topdressed control. The total N losses as volatilized NH3 ranged from 2.2% (calcium nitrate) to 4.5% (urea+zeolite). The N loss as volatilized NH3 from urea was very low (3.2%), with no significant difference between urea+zeolite, ammonium sulfate and calcium nitrate. Significantly, higher cumulated N2O emissions were observed with ammonium sulfate than with the control. No significant differences among fertilizers were found for emission factor (EF), which was 0.20% on average (0.14-0.26%), indicating that use of IPCC default EF (1.00%) would substantially overestimate N2O emission. Free drainage and acidity of Oxisols and occurrence of dry spells, known as 'veranicos', are characteristics of Cerrado biome that may naturally mitigate N2O emissions.
