In weathered tropical and subtropical soils organic matter is crucial for soil productivity and its quantity depends heavily on soil management systems. This study evaluated the effect of no-till cropping systems on organic matter content and quality in a sandy clay loam Acrisol soil (Paleudult in US taxonomy) from Southern Brazil. Ten cropping systems with varying additions of C and N were conducted for 12 years (from 1983 to 1994), The addition of crop residues increased total organic carbon (TOC) and total nitrogen (TN) in the soil at 0-17.5 cm depth, and this increase was directly related with C and N added or recycled by the systems. The crop residues added to the soil were associated with reduced semiquinone free radical concentration, detected by electron spin resonance (ESR), in the organo-mineral aggregates <53 mu m and humic acid (HA) samples, in the soil at 0-2.5 cm depth. This showed that stable organic matter originating from crop residues was less humidified than the original soil organic matter. Results obtained from organo-mineral aggregates showed a higher amplitude (highest and lowest values were 5.47 and 2.09 x 10(17) spins g(-1) of TOC, respectively) of semiquinone free radical concentration than HA samples (highest and lowest values were 2.68 and 1.77 x 10(17) spins g(-1) of HA, respectively). These data showed that alterations due to tillage in soil organic matter characteristics, e.g,, humification degree can be better identified through a combination of soil physical fractionation and spectroscopic analysis. Semiquinone content in the HA samples, detected by ESR, related significantly to aromaticity, as measured by nuclear magnetic resonance (NMR) of C-13. Management systems including no-till and cropping systems with high C and N additions to the soil improved its quality in Southern Brazil. (C) 2000 Elsevier Science B,V. All rights reserved.
