International initiatives such as the United Nations Framework Convention on Climate Change and the Kyoto Protocol require that countries calculate national inventories of their greenhouse gas emissions. The objective of the present study was to develop a country-specific (Tier II) methodology to calculate the inventory of N2O emissions from agricultural soils in Canada. Regional fertilizer-induced emission factors (EFreg) were first determined using available field experimental data. Values for EFreg were 0.0016 kg N2O-N kg-1 N in the semi-arid Brown and 0.008 kg N2O-N kg N-1 in the sub-humid Black soil zones of the Prairie region, and 0.017 kg N2O-N kg-1 N in the humid provinces of Quebec and Ontario. A function relating EFreg to the "precipitation to potential evapotranspiration" ratio was determined to estimate annual emission factors (EFeco) at the ecodistrict scale in all agricultural regions of Canada. Country-specific coefficients were also developed to account for the effect of several additional factors on soil N2O emissions. Emissions from fine-textured soils were estimated as being 50% greater than from coarse- and medium-textured soils in eastern Canada; emissions during winter and spring thaw corresponded to 40% of emissions during the snow-free season in eastern Canada; increased emissions from lower (wetter) sections of the landscape and irrigated areas were accounted for; emissions from no-till soils were 10% greater in eastern, but 20% lower in western Canada than from those under conventional tillage practices; emissions under summerfallow were estimated as being equal to those from soils under annual cropping. This country-specific methodology therefore accounts for regional climatic and land use impacts on N2O emission factors, and includes several sources/offsets that are not included in the Intergovernmental Panel on Climate Change (IPCC) default approach.
